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Reactivity of the Mo(O)(S) functional group in the [(L)Mo(O)(.mu.-S)2Mo(O)(S)]n- dimeric thiomolybdate complexes, (L = C5H5-, n = 1; S42-, n = 2) and implications regarding the function of xanthine oxidase. Synthesis and structural characterization of [(DMF)3Mo(O)(.mu.-S)2Mo(O)(S2)], [Ph4P][(C5H5)Mo(O)(.mu.-S)2Mo(O)(S2)], [Ph4P]2[(S4)Mo(O)(.mu.-S)2Mo(O)(S)] and (Et4N)4{[(S4)Mo(O)(.mu.-S)2Mo(O)(S)]2}

Reactivity of the Mo(O)(S) functional group in the [(L)Mo(O)(.mu.-S)2Mo(O)(S)]n- dimeric thiomolybdate complexes, (L = C5H5-, n = 1; S42-, n = 2) and implications regarding the function of xanthine oxidase. Synthesis and structural characterization of [(DMF)3Mo(O)(.mu.-S)2Mo(O)(S2)], [Ph4P][(C5H5)Mo(O)(.mu.-S)2Mo(O)(S2)], [Ph4P]2[(S4)Mo(O)(.mu.-S)2Mo(O)(S)] and (Et4N)4{[(S4)Mo(O)(.mu.-S)2Mo(O)(S)]2}

Coucouvanis, D.; Toupadakis, A.; Lane, J. D.; Koo, S. M.; Kim, C. G.; Hadjikyriacou, A.
  • 期刊名称Journal of the American Chemical Society
  • 作者Coucouvanis, D.; Toupadakis, A.; Lane, J. D.; Koo, S. M.; Kim, C. G.; Hadjikyriacou, A.
  • 卷第113卷
  • 期第14期
  • 印刷ISSN0002-7863
  • 文件大小1584.21KB
  • 发表时间1991-07
  • DOI10.1021/ja00014a021
  • 页码5271-5282
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