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Lewis-Acid Properties of Technetium(VII) Dioxide Trifluoride, TcO
              <sub/>2</sub>
              F
              <sub/>3</sub>
              :  Characterization by
              <sup>19</sup>
              F,
              <sup>17</sup>
              O, and
              <sup>99</sup>
              Tc NMR Spectroscopy and Raman Spectroscopy, Density Functional Theory Calculations of TcO
              <sub/>2</sub>
              F
              <sub/>3</sub>
              , M
              <sup>+</sup>
              TcO
              <sub/>2</sub>
              F
              <sub/>4</sub><sup>-</sup>
              [M = Li, Cs, N(CH
              <sub/>3</sub>
              )
              <sub/>4</sub>
              ], and TcO
              <sub/>2</sub>
              F
              <sub/>3</sub>
              ·CH
              <sub/>3</sub>
              CN, and X-ray Crystal Structure of Li
              <sup>+</sup>
              TcO
              <sub/>2</sub>
              F
              <sub/>4</sub><sup>-</sup>
               
              <sup>†</sup>

Lewis-Acid Properties of Technetium(VII) Dioxide Trifluoride, TcO 2 F 3 :  Characterization by 19 F, 17 O, and 99 Tc NMR Spectroscopy and Raman Spectroscopy, Density Functional Theory Calculations of TcO 2 F 3 , M + TcO 2 F 4- [M = Li, Cs, N(CH 3 ) 4 ], and TcO 2 F 3 ·CH 3 CN, and X-ray Crystal Structure of Li + TcO 2 F 4-   †

Casteel, William J.; Dixon, David A.; LeBlond, Nicolas; Mercier, Hélène P. A.; Schrobilgen, Gary J.
  • 期刊名称Inorganic Chemistry
  • 作者Casteel, William J.; Dixon, David A.; LeBlond, Nicolas; Mercier, Hélène P. A.; Schrobilgen, Gary J.
  • 卷第37卷
  • 期第2期
  • 印刷ISSN0020-1669
  • 电子ISSN1520-510X
  • 文件大小289.83KB
  • 发表时间1998-01
  • DOI10.1021/ic9708935
  • 页码340-353
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