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Aminoallenylidene complexes of ruthenium(ii) from the regioselective addition of secondary amines to butatrienylidene intermediates: a combined experimental and theoretical study of the hindered rotation around the CN-bondElectronic supplementary information (ESI) available: IR spectra recorded during the reduction of complex 2b and the subsequent reoxidation (Fig. S1), UV/Vis spectroelectrochemical investigation of the reduction of compound 2b (Fig. S2) and the calculated energy profile of trans-[Cl(dhpm)2RuC3{N(CH3)2}(CH3)]+ with a planar N(CH3)2 group upon rotation around the C?N bond (Fig. S3). See http://www.rsc.org/suppdata/dt/b2/b211774f/

Aminoallenylidene complexes of ruthenium(ii) from the regioselective addition of secondary amines to butatrienylidene intermediates: a combined experimental and theoretical study of the hindered rotation around the CN-bondElectronic supplementary information (ESI) available: IR spectra recorded during the reduction of complex 2b and the subsequent reoxidation (Fig. S1), UV/Vis spectroelectrochemical investigation of the reduction of compound 2b (Fig. S2) and the calculated energy profile of trans-[Cl(dhpm)2RuC3{N(CH3)2}(CH3)]+ with a planar N(CH3)2 group upon rotation around the C?N bond (Fig. S3). See http://www.rsc.org/suppdata/dt/b2/b211774f/

Winter, Rainer F.; Hartmann, Stephan; Z�li?, Stanislav; Wilhelm Klinkhammer, Karl
  • 期刊名称Dalton Transactions
  • 作者Winter, Rainer F.; Hartmann, Stephan; Z�li?, Stanislav; Wilhelm Klinkhammer, Karl
  • 期第11期
  • 印刷ISSN1477-9226
  • 电子ISSN1477-9234
  • 文件大小396.94KB
  • 发表时间2003
  • DOI10.1039/b211774f
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