Nanosized Au2Pd41(CO)27(PEt3)15 containing two geometrically unprecedented 13-coordinated Au-centered (�13-Au)Pd13 polyhedra connected by triangular face-sharing and three interpenetrating 12-coordinated Pd-centered (�12-Pd)Au2Pd10 icosahedra: geometrical change in centered polyhedra induced by Au/Pd electronegativity-mismatchDedicated by L. F. D. to Fred Basalo on the occasion of his 83rd birthday in recognition of his highly illustrious scientific career in Inorganic Chemistry at Northwestern University and his tremendous impact as a researcher, educator, scholar, and inspirational leader.

Tran, Nguyet T.; Powell, Douglas R.; Dahl, Lawrence F.

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