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Borohydride, Azide, and Chloride Anions As Terminal Ligands on Fe/Mo/S Clusters. Synthesis, Structure and Characterization of [(Cl <sub/>4</sub> -cat)(PPr <sub/>3</sub> ) MoFe <sub/>3</sub> S <sub/>4</sub> (X) <sub/>2</sub> ] <sub/>2</sub> (Bu <sub/>4</sub> N) <sub/>4</sub> and [(Cl <sub/>4</sub> -cat)(PPr <sub/>3</sub> )MoFe <sub/>3</sub> S <sub/>4</sub> (PPr <sub/>3</sub> )(X)] <sub/>2</sub> (Bu <sub/>4</sub> N) <sub/>2</sub> (X = N <sub/>3</sub><sup>-</sup> , BH <sub/>4</sub><sup>-</sup> , Cl <sup>-</sup> ) Double-Fused Cubanes. NMR Reactivity Studies of [(Cl <sub/>4</sub> -cat)(PPr <sub/>3</sub> ) MoFe <sub/>3</sub> S <sub/>4</sub> (BH <sub/>4</sub> ) <sub/>2</sub> ] <sub/>2</sub> (Bu <sub/>4</sub> N) <sub/>4</sub>

Borohydride, Azide, and Chloride Anions As Terminal Ligands on Fe/Mo/S Clusters. Synthesis, Structure and Characterization of [(Cl 4 -cat)(PPr 3 ) MoFe 3 S 4 (X) 2 ] 2 (Bu 4 N) 4 and [(Cl 4 -cat)(PPr 3 )MoFe 3 S 4 (PPr 3 )(X)] 2 (Bu 4 N) 2 (X = N 3- , BH 4- , Cl - ) Double-Fused Cubanes. NMR Reactivity Studies of [(Cl 4 -cat)(PPr 3 ) MoFe 3 S 4 (BH 4 ) 2 ] 2 (Bu 4 N) 4

Koutmos, Markos; Georgakaki, Irene P.; Coucouvanis, Dimitri
  • 期刊名称Inorganic Chemistry
  • 作者Koutmos, Markos; Georgakaki, Irene P.; Coucouvanis, Dimitri
  • 卷第45卷
  • 期第9期
  • 印刷ISSN0020-1669
  • 电子ISSN1520-510X
  • 文件大小367.00KB
  • 发表时间2006-05
  • DOI10.1021/ic052156b
  • 页码3648-3656
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