Bioinspired Hydrogenase Models: The Mixed-Valence Triiron Complex [Fe
<sub/>3</sub>
(CO)
<sub/>7</sub>
(μ-edt)
<sub/>2</sub>
] and Phosphine Derivatives [Fe
<sub/>3</sub>
(CO)
<sub/>
7–
<i>x</i>
</sub>
(PPh
<sub/>3</sub>
)
<sub/><i>x</i>
</sub>
(μ-edt)
<sub/>2</sub>
] (
<i>x</i>
= 1, 2) and [Fe
<sub/>3</sub>
(CO)
<sub/>5</sub>
(κ
<sup>2</sup>
-diphosphine)(μ-edt)
<sub/>2</sub>
] as Proton Reduction Catalysts

Bioinspired Hydrogenase Models: The Mixed-Valence Triiron Complex [Fe ₃ (CO) ₇ (μ-edt) ₂ ] and Phosphine Derivatives [Fe ₃ (CO) _{7–
x} (PPh ₃ ) _x (μ-edt) ₂ ] ( x = 1, 2) and [Fe ₃ (CO) ₅ (κ ² -diphosphine)(μ-edt) ₂ ] as Proton Reduction Catalysts

Rahaman, Ahibur; Ghosh, Shishir; Unwin, David G.; Basak-Modi, Sucharita; Holt, Katherine B.; Kabir, Shariff E.; Nordlander, Ebbe; Richmond, Michael G.; Hogarth, Graeme